![]() Cathy O’Neil, author of “Weapons of Math Destruction” on how data can lead us astray–from HR to Wall Street. She then chucked it and switched over to the private sector. in math from Harvard, was postdoc at the MIT math department, and a professor at Barnard College where she published a number of research papers in arithmetic algebraic geometry. Cathy O'Connor CPA, Finance Manager, CFO Walnut Grove, California, United States 44 followers 40 connections Join to view profile SI Consulting About Certified Public Accountant with 25 years of. In 1946, O’Donnell’s second film role was the highly-acclaimed “The Best Years of Our Lives,”.
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![]() ![]() Ĭhen X, Li J, Jia C (2019) Thermodynamic properties of gaseous carbon disulfide. Just toxic or also bioregulatory and/or therapeutic? Chem Soc Rev 46:21–39. ĭeMartino AW, Zigler DF, Fukuto JM, Ford PC (2017) Carbon disulfide. Zhang X, Ponce V, Galvez-Aranda DE, Zhou G, Zhou H, Seminario JM (2021) CS 2 removal from C 5 distillates by reactive molecular dynamics simulations. Yue X, Wang H, Kong J, Li B, Yang J, Li Q, Zhang J (2020) A novel and green sulfur fertilizer from CS 2 to promote reproductive growth of plants. Liu N, Song X, Wang C, Li K, Ning P, Sun X, Wang F, Ma Y (2020) Surface characterization study of corn-straw biochar catalysts for the simultaneous removal of HCN, COS, and CS 2. Zeng Z, Dlugogorski BZ, Oluwoye I, Altarawneh M (2019) Combustion chemistry of carbon disulphide (CS 2). Wang W, Fan L, Wang G (2017) Carbon disulfide (CS 2) adsorption and dissociation on the Cu(100) surface: a quantum chemical study. Our results might contrite to provide a novel method to study the catalytic hydrolysis of CS 2. During the hydrolysis of CS 2, the five reaction paths are parallel and competitive. It was sought out that the hydrolysis of CS 2 was an exothermic reaction, and the increment in temperature was adverse to the reaction. Besides, to further clarify which reaction path is better, the hydrolysis kinetics of CS 2 was analyzed. Apart from this, to further explore the reaction of CS 2 hydrolysis, the natural bond orbital (NBO) analysis of the transition states was carried out. Similarly, the order of the barriers for the three paths in the second reaction is C = S path < C = S path and C = O path < C = O path. In the reaction’s first step, the rate-determining step in both the single C = S path and the double C = S path possesses a higher barrier of 199.9 kJ/mol however, the 127.9 kJ/mol barrier in the double C = S path is lower than the 142.8 kJ/mol in the single C = S path. Hydrogen migration is crucial to the mechanism of CS 2 hydrolysis. Through optimizing the structure of reactants, intermediates, transition states, and products, it can be seen that the first step of CS 2 is that CS 2 reacts with H 2O first to form COS intermediate and the second step is COS intermediate reacts with H 2O to form H 2S and CO 2. Significant safety data come from the viscose rayon Industry, where both carbon disulfide as well as small amounts of H 2S may be present.Density functional theory (DFT) is used to look into the two-step hydrolysis mechanism of CS 2. In 2007 Alfa Aesar stopped selling carbon disulfide samples.Īt very high levels, carbon disulfide may be life-threatening because it affects the nervous system. Dilution with nitrogen rendered contents nonflammable. Johnson Matthey's sister company Alfa Aesar was the first company to introduce carbon disulfide in the form of pressurized bottle containing a solution of pressurized nitrogen, coupling agent, stablizer, and carbon disulfide, with an active carbon disulfide content of 85%. Worldwide exports of this chemical are negligible. Commercial AvailabilityĬS 2, being highly flammable and having one of the lowest autoignition temperatures, cannot be transported easily using commercial means. This conversion proceeds via the intermediacy of thiophosgene, CSCl 2.ĬS 2 is a ligand for many metal complexes, forming pi complexes. Sodium reduces CS 2 to give the heterocycle "dmit 2-": 3 CS 2 + 4 Na → Na 2C 3S 5 + Na 2Sĭirect electrochemical reduction affords the tetrathiooxalate anion: 2 CS 2 + 2e - → C 2S 4 2- ChlorinationĬhlorination of CS 2 is the principal route to carbon tetrachloride: CS 2 + 3 Cl 2 → CCl 4 + S 2Cl 2 Both xanthates and the related thioxanthates (derived from treatment of CS 2 with sodium thiolates) are used as flotation agents in mineral processing. This reaction is the basis of the manufacture of regenerated cellulose, the main ingredient of viscose, rayon and cellophane. Nucleophiles such as amines afford dithiocarbamates: It is widely used in the synthesis of organosulfur compounds such as Metham sodium, a soil fumigant. These differences in reactivity can be attributed to the weaker π donor-ability of the sulfido centers, which renders the carbon more electrophilic. Although it is isoelectronic to carbon dioxide, CS 2 is highly flammable:Ĭompared to CO 2, CS 2 is more reactive toward nucleophiles and more easily reduced. The reaction is analogous to the combustion of methane. A lower temperature reaction, requiring only 600 ☌ utilizes natural gas as the carbon source in the presence of silica gel or alumina catalysts: CH 4 + 1/2 S 8 → CS 2 + 2 H 2S CS 2 once was manufactured by combining carbon (or coke) and sulfur at high temperatures. Small amounts of carbon disulfide are released by volcanic eruptions and marshes. 3.1 Pressurized Liquid Nitrogen Based Sample. ![]() ![]() Cobalt one of the essential Alabama Gulf Coast restaurants according to Alabama News Center. Cobalt named one of nine delicious restaurants near Gulf Shores according to travel writer Kathleen Walls. Please note, our efforts to provide the most accessible and usable web experience are ongoing. 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![]() ![]() Simply closing and reopening the program can often alleviate issues because the program “flushes” the processes it may be hung on and then initializes them again. Complex software like NLEs tie up vast system resources, including the CPU, memory, storage, GPUs, and network bandwidth, which can naturally cause a performance hit and choppy playback performance after long editing sessions. It may seem trivial, but sometimes Premiere Pro or your machine just needs a fresh start. Clear Premiere Pro’s preferences and plugins. ![]() If you’ve ever experienced playback problems, export errors, or irregular performance, hopefully this guide will spare you future frustration, and get you on the right path to NLE creative harmony. In today’s article, I’ll walk through some common issues and solutions in Adobe Premiere Pro and show you how to fix them. So let’s learn to take charge of our tools. Because when you’re two days from client review, the last thing you need is to waste hours browsing old forum posts for technical help. So even though troubleshooting a printer is not something most editors are prepared for, troubleshooting NLE problems is something we should all practice. Particularly for us in the post-production world, this inevitably seems to happen at the tail-end of a project when everything is due for delivery. Technology, like people, has bad days from time to time. And if this hasn’t happened to you, it’s coming. Or at the least, Premiere Pro’s playback gets choppy and stuttery. ![]() We’ve all been there before the network goes down, your workstation won’t boot, or your NLE of choice crashes every time you right-click, and suddenly your workday comes to a screeching halt. ![]() ![]() ![]() You’ll spend less time waiting and more time streaming, sharing, and downloading.To resolve issues with the Apple Airport dropping Source-Connect connections please use at least version 3.8. This is especially problematic if you live in a crowded area, such as an apartment block with multiple routers nearby.Īccording to Google, “ High traffic on a single channel can slow down Wi-Fi speed, so OnHub regularly scans the environment and switches to a different channel if it detects interference from other devices. It’s using this power to scan for networks every five minutes. Most networking problems are caused by multiple WiFi networks working against each other. ![]() It actually matches some smartphones (and older computers) for specs. It has some great specs for a router, including a dual-core 1.4GHz processor, 1GB of RAM and 4GB of storage. So far this sounds like Apple’s AirPort and Express devices. What seperates Googe OnHub is the built-in smarts. These mesh together to get rid of any dead zones you might have. Google is promising a new approach to WiFi with OnHub. Rather than just buying a single router, the idea is that you place multiple hubs around your house. The iPhone and iPad app is especially great for anyone who has used the clunky web-based interfaces offered by most modems routers.īest Apple WiFi router for iPhone, Mac buying guide: AirPort Extreme ![]() You can set up, manage and update your wireless router using Apple’s AirPort Utility for Mac OS X and iOS devices. The Time Capsule also has a drive built in so you can backup files directly. You can attach an external hard drive and use to share and access files wirelessly. You can attach a printer to the base station and print wirelessly from a Mac or iOS device. Both the AirPort Time Capsule and AirPort Extreme feature dual internal antennas so they can produce both a 2.4GHz and 5GHz wireless network. The latest standard in wireless networking compatible with Macs and Macbooks released after June 2013. ![]() In this review, we look at what the three AirPort WiFi routers have to offer and the differences between them, and offer advice as to which Apple router is right for you.Īpple currently makes the following AirPort base station devices: Which Apple router should you buy – which router is best for your requirements? The choice isn’t as straightforward as you might think, because each AirPort base station offers a different set of features, strengths and weaknesses (and is priced accordingly). Google has information aboutīest Apple WiFi router for iPhone, Mac buying guide: Buying an Apple router You control it via an app on your iPhone (or Google Android phone). But it’s just released its Google OnHub router: a $200 cylinder that promises a “new way to Wi-Fi”.
![]() ![]() If you're looking for a serious gaming powerhouse with the fastest display and coolest look for gamers, that's going to be the top phone on our list. If you play a lot on the go and need amazing battery life and fast charging, look for a phone with a big battery and high wattage charging. If your games benefit from extra controls, you might consider a phone with shoulder buttons. When you're choosing a gaming phone, you need to think about which games you like to play. How to choose the best gaming phone for you Its 6.7-inch 120Hz screen is large and high quality too, so games will look good, and its battery life exceeds that of most non-gaming phones, so you won’t need to plug it in too often. Add to that the wealth of games available on the App Store – not to mention the Apple Arcade subscription service – and this is a clear winner on the gaming front. Plus, more games will be well optimized for this phone than a lot of the Android competition, since it’s such a popular handset. That power can translate to better quality graphics and improved frame rates. The iPhone 14 Pro Max is one of the very best conventional smartphones for gaming, as while it might lack gaming-specific features like physical triggers, it has something no dedicated gaming phone has access to – the A16 Bionic chipset.īenchmarks suggest this is more powerful than anything Qualcomm, Samsung or MediaTek can muster, so for sheer power the iPhone 14 Pro Max is a top choice. It's worth noting also that there's now native Xbox and PlayStation controller support on both iOS and Android, so although the following phones don't - for the most part - have dedicated gaming peripherals from their makers, they do support some existing peripherals. You'll find a lot of overlap with our best phones list, for good reason: these handsets have top-end specs and screens to give the best gaming experience possible outside of gaming-focused phones. We've suggested the best phones designed for gaming, but if you'd rather have a more mainstream device, here are all the phones we recommend that, among the rest of their strengths, are also very good phones to play games on. Read our review: Black Shark 4 Pro The best non-gaming phones for gaming It even manages more than a day between charges. A 144Hz refresh rate means the action is always silky smooth here, while a Snapdragon 888 processor keeps the action sailing at all times.Ī dedicated gaming app in the form of Shark Space rounds things off nicely, allowing you to focus on your gaming time. Sporting a 6.67-inch Super AMOLED screen, it's a great option for those that want to see their games shine too. ![]() As with other Black Shark phones, it has integrated gaming triggers that pop-out and can be customized to do what you need them to do. We’re constantly updating this list as well, so check back soon if you're not set on any of the options here.īulky it might be but the Black Shark 4 Pro has a lot to love here. Once you know what phone to buy, check out our look at the best iPhone games and best Android games to find plenty of titles to play. Take a look at the best gaming phones below. Having tested more than our share of phones, we've ranked all the best gaming phones, prioritizing those that are specifically designed with gaming in mind, followed by more general smartphones that come with enough power to give you a smooth and immersive gaming experience. Phones like the Asus ROG Phone 6D offer all these features, for example, which is why it tops our list of the best gaming phones. That's especially if you spend more of your free time gaming and you want that distinctive gamer aesthetic.Ī dedicated device tends to boast better cooling as well as come with shoulder triggers and even detachable physical controls. So, while some of the best smartphones, such as the iPhone 14 Pro Max and Sony Xperia 1 IV, might do a great job tackling mobile games, you're better off getting a gaming phone for a better gaming experience. ![]() ![]() ![]() UN official says US had Boston attack coming.IDF rabbinate removes controversial 'Laws of Mezuz.Finance Minister Yair Lapid: No math, no cash.Israel’s chief rabbinate says oral suction at circ.Outrage after politician calls ultra-Orthodox ‘par.Israel - Attorney General: OK To Check Emails Of F.Qatar - Top Sunni Cleric Boycotts Conference Refus.Judge to weigh rabbi's bid to defend self in slay.Haredi group: Resist draft with all your soul.Rabbinical judge suspected of abuse of power.Western Wall rabbi: Sharansky plan might be no good.Lag Baomer: Traditional Torah Walk in Tzfat.Oy Vey! Republicans in Florida Want to Ban Orthodo.KIRYAS JOEL - 50,000 expected for Lag Ba’omer.Julio Acevedo, 'Hit and run driver who killed Ort.Petition to keep John Galliano from teaching at Pa.NY Post Editorial Slams City For Going After Jewis. ![]()
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![]() ![]() There’s so much more to do! Check out Visit Indy for nightlife ideas and a list of upcoming events. ![]() See your favorite national acts at Ruoff Home Mortgage Music Center, Banker’s Life Fieldhouse or Old National Centre.In the mood for a little dueling piano? Check out Brick House or Howl at the Moon.Elmo Steakhouse and Harry & Izzys 100 Best Steakhouses in America for 2016. Take in live jazz at the Jazz Kitchen, Slippery Noodle Inn and the Chatterbox. Well be back in 2017 as a regional restaurant experience - Devour Indy.Cheer on Indy’s home teams at Champps, Moe & Johnny’s, Kilroy’s or Scotty’s.Dance the night away at The Vogue, The Red Room, Social, White Rabbit Cabaret or Metro.At Blend Bar, enjoy the fully stocked humidor featuring Davidoff cigars, bourbon, single malt scotch, fine wine/ports and the only Diamond Crown cigar lounge in Indianapolis.Not to be missed!Įnd a day of shopping and dining with a night on the town! From comedy clubs to karaoke to brewpubs to dancing to cigar bars, Indy has it all! Devour Indy offers one of the best ways to sample dozens of Indianapolis’ great restaurants at a great price.Indy abounds with craft breweries! A few to try: Tow Yard Brewing, Four Day Ray, Sun King Brewing, Flat12 Bierworks and Fountain Square Brewing Company. Location & Hours 200 S Meridian St Ste 350 Indianapolis, IN 46225 Mile Square Get directions Edit business info You Might Also Consider Sponsored Kicasso Sneaker Art Bar 14 7.6 miles away from Devour Indy Donna B.Sample the best German food and beers while enjoying fun live bands at the Rathskeller’s Kellerbar and biergarten.Enjoy a yummy brunch every weekend at favorites Eggshell Bistro, Milktooth, Café Patachou and Taste Café.Indulge in the Batali, named one of the country’s best 10 sandwiches by Bon Appetit, at Goose The Market.Searching for a pizza that’s far from ordinary? Try Bazbeaux or Jockomo Upper Crust Pizza or Napolese.Elmo’s, Italian at Mama Carolla’s, not to mention Indian, Japanese, Thai, Mongolian, Ethiopian, French, Mexican and much more. With everything from the traditional to eclectic, you can indulge your taste buds with burgers at The Working Man’s Friend, steak and the famous shrimp cocktail at St.While some of our favorite and iconic Indy restaurants are listed below, we also encourage you to check Visit Indy for curated restaurant lists, as well as Indianapolis Monthly, which also regularly covers Indy’s hot food spots. Indianapolis’ local dining scene has exploded the past few years, resulting in the Circle City being recognized as a haven for foodies. Dining & Nightlife in Indianapolis Indianapolis restaurants and dining ![]() ![]() ![]() If you’re planning a summer camping trip, keep in mind how powerful the wind might be in your location. It will be better for you if you filter it more. If you need to get water from the Lake Thunderbird, either wade out as far as you can or use a water filter with a long input line that you can throw farther out into the Lake Thunderbird. Moving streams carry less particle and biological debris, which tends to collect near the Lake Thunderbird’s margin. ![]() If possible, get your water from flowing streams that flow into or out of the Lake Thunderbird. More water, more water, more water! Water is plentiful, but there isn’t a drop to drink unless you pack a filter! You should always filter or treat Lake Thunderbird water with a UV purifier to eliminate bacteria, protozoa, and other pollutants that may make you ill, no matter how clean it seems. Packing things like Citronella candles might be useful if you’re camping right close to the Lake Thunderbird. Finding a spot with a little incline will be good since there will be less bugs in this location. An easy option is to camp a little distance from the water. Mosquitoes, in particular, flourish in still water, but they aren’t the only bugs interested in a bite. If Lake Thunderbird camping has a disadvantage, it is that standing water may attract a variety of mosquitoes and pests. Largemouth bass, crappie, sunfish, channel catfish, white bass, and saugeye are all plentiful. Lake Thunderbird is the park’s main attraction for most visitors. Hiking, biking, and horseback riding routes wind their way around the lake and into the natural landscapes that surround it. Each of the 11 campsites has a strategically situated bathhouse with heated showers. Throughout the park, there are restrooms with flush toilets. There are thirty campsites with full hookups. A disposal facility is available at each campsite. There are 271 campsites dispersed over 11 campgrounds in Lake Thunderbird State Park. Lake Thunderbird camping – How to get the best possible experience? The four-mile equestrian paths, which are available from sunset to dawn Wednesday through Sunday, include 12 challenges. The Discovery Cove Nature Center and equestrian paths are situated in the Clear Bay portion of Lake Thunderbird State Park. Lake Thunderbird State Park in Norman has equestrian trails And if you time your trek well, you’ll be treated to a spectacular sunset. You’ll get to see some amazing animals as well as stunning views of the lake. Hiking the trails is a terrific opportunity to get out and stretch your legs while also getting a good overview of the state park. You may learn to sail, compete in sanctioned races, or even attend a regatta. There are two marinas and a boathouse where you may discover a variety of boats that are ready to sail. Whether you’re an experienced boater or a novice, Lake Thunderbird State Park provides everything you need to have a fantastic day on the lake. After a day on the lake, we like hearing our visitors’ fish stories. Largemouth bass, crappie, sunfish, channel catfish, white bass, and sockeye are all abundant in the lake. Lake Thunderbird is an excellent location for casting a line and spending some time fishing. You’ll gain a whole different perspective on the State Park and cover more land in the same amount of time as a regular trek. Mountain bike routes in Lake Thunderbird State Park are fairly steep, which is a good break from central Oklahoma. Lake Thunderbird Trails for Bikingīiking is permitted on all of the routes around Lake Thunderbird. If you happen to get a look, Animal Planet will undoubtedly want to watch your footage! 3. While the existence of the Lake Monster is yet unknown, a freshwater octopus is said to live in the man-made lake. Search Lake Thunderbird for the Lake Monster. The Crow’s Secret Nature Center also offers a guided eagle tour! 2. From December through February, bald eagles may be seen. The bald eagle winter migratory route passes through the state park. Lake Thunderbird State Park is a great place to go eagle watching. Read: Is Traveling A Hobby? The Ultimate Guide To An Exciting Way Of Life Learn about the Downsides Of Traveling As A Hobbyħ Reasons to Visit Lake Thunderbird State Park 1. The Discovery Cove Nature Center in Lake Thunderbird State Park is closed Sunday through Wednesday. ![]() The Discovery Cove Nature Center at Lake Thunderbird State Park is open from 9:30 a.m. Lake Thunderbird State Park also has bathrooms, playgrounds, picnic shelters, rustic campsites, and a seasonal restaurant. Over 200 RV parking spots, including 30 with full hookups, are available at the campground. On Lake Thunderbird, there are two marinas (Calypso Cove Marina and Little River Marina), nine boat ramps, and two swim beaches. ![]() |